AbstractWe examined how climate variability affects the mobilization of material from six watersheds. We analyzed one to seven years of high‐frequency sensor data from a temperate ecosystem and a tropical rainforest. We applied a windowed analysis to correlate concentration‐discharge (C‐Q) behavior with climate anomalies, providing insight into how hydrological and biogeochemical processes change in response to climate variability. Positive precipitation anomalies homogenized the C‐Q responses for dissolved organic matter, nitrate, specific conductance and turbidity, indicating that hydrological processes dominate the C‐Q signal and watersheds act as “conveyor belts” of material. In contrast, drier and warmer conditions led to C‐Q behavior associated with variation in solute concentration, suggesting that biogeochemical processes are a primary control on solute export and their response to flow. Results indicate that climate variability can move watersheds along a continuum from transporter‐to‐transformer of biologically active solutes and responses can potentially vary by biome.
