AbstractWe report measurements of energized outflowing/bouncing ionospheric ions and heated electrons in the inner magnetosphere during a geomagnetic storm. The ions arrive in the equatorial plane with pitch angles that increase with energy over a range from tens of eV to > 50 keV while the electrons are field aligned up to ~1 keV. These particle distributions are observed during intervals of broadband low‐frequency electromagnetic field fluctuations consistent with a Doppler‐shifted spectrum of kinetic Alfvén waves and kinetic field line resonances. The fluctuations extend from L ≈ 3 out to the apogee of the Van Allen Probes spacecraft at L ≈ 6.5. They thereby span most of the L shell range occupied by the ring current. These measurements suggest a model for ionospheric ion outflow and energization driven by dispersive Alfvén waves that may account for the large storm time contribution of ionospheric ions to magnetospheric energy density.